Suggest to check that the radiator fan is working - if it's an electric fan, should be on when the A/C is running - if it's an engine driven fan, make sure the clutch is in good shape. Either way, should be good airflow whenever the A/C is on.
Making sure the condenser coil is clean is another check - as the previous poster mentions - make sure the bugs are cleared out.
If you have a coolant temperature gauge, it will likely show a little hotter with the A/C on, but should not be to the point of overheating.